. A commentary on the scientific writings of J. Willard Gibbs. Gibbs, Joniah Willard, 1839-1908; Science; Thermodynamics. 308 SCHREINEMAKERS AKT. H are unsaturated. If we imagine the liquid c represented by point c in Fig. 10, then the points of 2-c represent unsaturated hquids, whilst the points of c-2' represent supersaturated liquids which pass into the system (11). (iii) T{X) > T(W) > T > T{e) (case of Fig. 7). Since. Fig. 10 both the substances W and X are now solid we may imagine the systems L{u) + solid W, L(z) + solid X,] solid W + sohd X. (12) Besides the lines z'iX) discusse
. A commentary on the scientific writings of J. Willard Gibbs. Gibbs, Joniah Willard, 1839-1908; Science; Thermodynamics. 308 SCHREINEMAKERS AKT. H are unsaturated. If we imagine the liquid c represented by point c in Fig. 10, then the points of 2-c represent unsaturated hquids, whilst the points of c-2' represent supersaturated liquids which pass into the system (11). (iii) T{X) > T(W) > T > T{e) (case of Fig. 7). Since. Fig. 10 both the substances W and X are now solid we may imagine the systems L{u) + solid W, L(z) + solid X,] solid W + sohd X. (12) Besides the lines z'iX) discussed above, we must now imagine in Fig. 7 also the lines u'(W) and {W)(X), and we can now draw a tangent to the f-curve through each of the points (W) and (X). If g' and h' are the respective points of contact, we see that of all conceivable f-points of Fig. 7 only those of the tangents (W)g' and h'(X), and those of the part g'h' of the ^-curve, represent stable states. From this it follows that of all. Please note that these images are extracted from scanned page images that may have been digitally enhanced for readability - coloration and appearance of these illustrations may not perfectly resemble the original Donnan, F. G. (Frederick George), 1870-1956; Haas, Arthur Erich, 1884-1941. New Haven, Yale University Press; London, H. Milford, Oxford University Press
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