. Bulletin international de l'Académie des Sciences de Cracovie. Classe des sciences mathématiques et naturelles. = Anzeiger der Akadémie der Wissenschaften in Krakau. Mathematisch-naturwissenschaftliche classe. Science. 249 H-C, = K— H-C 3 N- 4 cbinoxaline -;7 3 6 2. N —/ ^3 1 Indophenazine B -C = N C D N - IN H 1 ps-Indohpenazi ne -G = N B 1 0 D C = N —I J2 \/ 1 C u maroph enazine. a—D,,3, — Chlo r oi ndoph en azi ne. Prepared by condensing- p-chloro-o-phenylenediamine with isatin in aequimoleeular proportions in acetic acid solution at the boiling température of the mixture. Light yellow ne


. Bulletin international de l'Académie des Sciences de Cracovie. Classe des sciences mathématiques et naturelles. = Anzeiger der Akadémie der Wissenschaften in Krakau. Mathematisch-naturwissenschaftliche classe. Science. 249 H-C, = K— H-C 3 N- 4 cbinoxaline -;7 3 6 2. N —/ ^3 1 Indophenazine B -C = N C D N - IN H 1 ps-Indohpenazi ne -G = N B 1 0 D C = N —I J2 \/ 1 C u maroph enazine. a—D,,3, — Chlo r oi ndoph en azi ne. Prepared by condensing- p-chloro-o-phenylenediamine with isatin in aequimoleeular proportions in acetic acid solution at the boiling température of the mixture. Light yellow needles or soales from alcohol. M. p. above 300°. Easily soluble in aceton and Chlo- roform. The alcoholic solution yields with ammoniac, silver nitrate solution a red precipitate. Analysis: gr. gave 22-8 cm^ N (p=742ww t=l8») found 16-46»/o N calcul, for CuHgNgCl - l(r677„ N y.—D., (3, — Chloro-Pr-acetylindophenazine may lie obtained by boiling the former with anhydrous acetic acid. It crystallises from alcohol in white needles, in whicb it is not very easily soluble. Aceton, benzène, ether and chloroform dis- solve it easily. M. p. 208". Analysis: gr. gave 150 cm^ N (t=14-5'' p=734)»MM found 14-49Vo 1^'- calcul, for Ci„H,„N3 0Cl 14-24 „. Please note that these images are extracted from scanned page images that may have been digitally enhanced for readability - coloration and appearance of these illustrations may not perfectly resemble the original Polska Akademia Umiejtnoci. Wydzia Matematyczno-Przyrodniczy. Cracovie : Impr. de l'Université


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