. American chemical journal . CH NH CH CH NH Carbazol. Relations existing between Carbazol and Pyrrol. 441 The analogy existing between indol and pyrrol has receivedimportant experimental demonstration from the researches ofV. Baeyer, E. Fischer, and Ciamician, but up to the present timeno material evidence has been accumulated to show that a similarrelation exists between carbazol and pyrrol. The formation ofcarbazol from thiodiphenylamine by the action of copper fur-nishes some proof in support of the formula given above; but asthis is the only reaction clearly tending to show that
. American chemical journal . CH NH CH CH NH Carbazol. Relations existing between Carbazol and Pyrrol. 441 The analogy existing between indol and pyrrol has receivedimportant experimental demonstration from the researches ofV. Baeyer, E. Fischer, and Ciamician, but up to the present timeno material evidence has been accumulated to show that a similarrelation exists between carbazol and pyrrol. The formation ofcarbazol from thiodiphenylamine by the action of copper fur-nishes some proof in support of the formula given above; but asthis is the only reaction clearly tending to show that carbazol is adi-ortho derivative of diphenyl, and therefore that it contains thepyrrol ring, further evidence in the same direction appearsdesirable. In making the experiments which led up to the facts here*recorded, I hoped to find points of resemblance between carbazoland pyrrol for which the ^NH group alone, independent of thepyrrol ring, would not account, and thus to confirm indirectly theabove formula of carbazol. Runge, the discoverer of pyrrol, observ
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Keywords: ., bookcentury1800, bookdecade1870, bookpublisherbalti, bookyear1879