. A commentary on the scientific writings of J. Willard Gibbs. Gibbs, Joniah Willard, 1839-1908; Science; Thermodynamics. HETEROGENEOUS EQUILIBRIUM 271 A^syci\^/io. /^OS/Cjr/VpO fe02Si0a t^O^Qt-MiO /^gO s/a, Fig. 6. The ternary system, H2O-K2O-8102-8102. This diagram shows the various boundary curves, which give the locus of the com- position of the liquid phase in the various univariant equilibria. The mvariant (quintuple) points are designated by the letter Q; the numbers on the curves are the same in Figs. 6, 7, and 8. Following is a list of phases stable along each curve. Curve 2. V -f L -
. A commentary on the scientific writings of J. Willard Gibbs. Gibbs, Joniah Willard, 1839-1908; Science; Thermodynamics. HETEROGENEOUS EQUILIBRIUM 271 A^syci\^/io. /^OS/Cjr/VpO fe02Si0a t^O^Qt-MiO /^gO s/a, Fig. 6. The ternary system, H2O-K2O-8102-8102. This diagram shows the various boundary curves, which give the locus of the com- position of the liquid phase in the various univariant equilibria. The mvariant (quintuple) points are designated by the letter Q; the numbers on the curves are the same in Figs. 6, 7, and 8. Following is a list of phases stable along each curve. Curve 2. V -f L -f- K20-48i02-H20 + SiOj -I- K20-28i02-H20 + KjO-48102-HiO -I- K20-2Si02 -I- K20-4S102-H20 + KjOSiOi-HjO + K20-2S102H20 -I- K20-S102-^H20 + K20-28i02-H20 + K20-8i02-^H20 + K20-28102 -I- KjO-SlOj + KjO-28102 + K20Si02 4H20 + KjO-28102 HjO -|- K20-2810, 7b. V + L -f- K20-28102•H2O + K20-28i0j Curve Curve Curve Curve Curve Curve Curve Curve 4a. 4b. 6a. 6b. 6c. 6d. 7a. 7a V V V V V V V 4- L L L L L L -1- KjO^SiOjHsO Curve 7b + 7c. V + L + K20-2Si02H20 + K20-28102 Curve 7a -I- 7b 4- 7c. V -f- K20-28102-H20 -|- K20-28102, in binary system, HjO-KzO-28102 Curve 8a. V-f K20-8102-H2O-f K20-8102-§H20-|-KjO-28102-HzO Curve 8b. V + L -f- K20-8i02H20 + K20-8102-^H20 Curve 8a -|- 8b. V -f- K20-8i02-H20 -}- K20-8102-^H20, in binary system, H20-K20-8102 Curve 9. V + KzO-48102•H2O -|- K2O-48102 -|- 8iOj Curve 10a. V -|- K20-8102-§H20 + K2O-8IO2 -f K20-28i02 Curve 10b. V -i- L + K20-8i02-§H20 + K2O-8IO2 Curve 10a -|- 10b. V -|- K20-8102-iH20 + K2O-SIO2, in binary sys- tem, H20-K20-8i02 Curve 11. V + L -h K2O-28IO2 -|- K20-48102 Curve 12. V + L -f- KjO-48102 + 810,. Please note that these images are extracted from scanned page images that may have been digitally enhanced for readability - coloration and appearance of these illustrations may not perfectly resemble the original Donnan, F. G. (Frederick George), 1870-1956; Haas, Arthur Erich, 1884-1941. New Haven, Yale University Press;
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Keywords: ., bookcentury1900, booksubjectscience, booksubjectthermodynamics
