. A commentary on the scientific writings of J. Willard Gibbs. Gibbs, Joniah Willard, 1839-1908; Science; Thermodynamics. 314 SCHREINEMAKERS ART. H T(c) a critical solution temperature. This temperature may be higher or lower than T{X). 16. The line zu2' and the curves hz, zcu and uT{X) divide Fig. 12 into fields, the meaning of which follows from the preceding considerations. At the same time it is apparent that the field zcu, , the heterogeneous two-liquid phase field, does not end at the line zu but extends farther downwards, although in a metastable condition. As the liquids saturated.


. A commentary on the scientific writings of J. Willard Gibbs. Gibbs, Joniah Willard, 1839-1908; Science; Thermodynamics. 314 SCHREINEMAKERS ART. H T(c) a critical solution temperature. This temperature may be higher or lower than T{X). 16. The line zu2' and the curves hz, zcu and uT{X) divide Fig. 12 into fields, the meaning of which follows from the preceding considerations. At the same time it is apparent that the field zcu, , the heterogeneous two-liquid phase field, does not end at the line zu but extends farther downwards, although in a metastable condition. As the liquids saturated. Fig. 12 with respect to X are represented by the curves hz and uT(X), the solubihty of X at T(s) does not change continuously but jumps from z to u. If, however, we also consider metastable and unstable states, then a continuous transition from z to u exists. The saturation curve of X consists, as we shall presently show, of a curve hzgekuT{X) having a maximum temperature in g and a minimum temperature in k. In order to prove this, we at first imagine T = T(s), so that (X) in Fig. 11 coincides with s. Besides the two coincident. Please note that these images are extracted from scanned page images that may have been digitally enhanced for readability - coloration and appearance of these illustrations may not perfectly resemble the original Donnan, F. G. (Frederick George), 1870-1956; Haas, Arthur Erich, 1884-1941. New Haven, Yale University Press; London, H. Milford, Oxford University Press


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