Correlation of ionization and structure . 1. CORRELATION OP IONIZATION AND Introduction - Recent problems in the field of organic chemis-try have caused the search for new methods for the determination of thechemical structure of organic compounds. The tendency is towardsphysico-chemical methods, different chemists using different physicalconstants. As an example Ostwald (1) and later Wegscheider (2) haveemployed the ionization constants of organic electrolytes. Other constants such as the specific rotation of optically ac-tive compounds, magnetic rotation, molecular refraction, et
Correlation of ionization and structure . 1. CORRELATION OP IONIZATION AND Introduction - Recent problems in the field of organic chemis-try have caused the search for new methods for the determination of thechemical structure of organic compounds. The tendency is towardsphysico-chemical methods, different chemists using different physicalconstants. As an example Ostwald (1) and later Wegscheider (2) haveemployed the ionization constants of organic electrolytes. Other constants such as the specific rotation of optically ac-tive compounds, magnetic rotation, molecular refraction, etc. have beensuccessfully employed in certain cases. A comparison between these physical methods for the determina-tion of structure and the chemical ones is not out of place. In thechemical methods fairly large amounts of the substance are required foranalysis. This requisite proves to be a handicap in most instances,for very often the yield of the substance under investigation is verypoor. Again these chemical methods destroy the substacorrelationofion00carr
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